1st semester reaction review KEY PDF

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Summary examples of common reactions displayed in semester 1 ...

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CHE 3310-001

KEY Reaction Review Determine typical organic starting materials and products that correspond to each of the following reaction conditions:

C

Br

Br2

C

H2O

C

C

C

OH

H

HO

H2SO4

C

NO2

HNO3

R

C

R(H)

SO3H

cat. H2SO4

NaBH4

H

CH3OH

R

OH C

1. BH3•THF

C C

C

SO3

H2SO4 O

C

heat

C

2. NaOH (aq),

C

R(H)

1. OsO4

C

C

2. Na2SO3

C OH

HO

C OH

H

Ag+ or Cu+2

H2O2

RCHO

RCO2H

O O O O O

C

R

R(H)

H Mg

CH3I

X C C H

NaOH or RONa

peroxides heat

H R

OH C

R C C H

Nu

(CH3)3CO- K+

2° alcohol

H2CrO4

R(H)

C C

ketone carb. acid

1° alcohol

O C C R

C

O

HCN R(H)

cat. NaCN

C

R

R(H)

polystyrene C

C

1. O3 2. (CH3)2S

C

O

+

O C

O R

NaNH2

C

C

CH3

PCC

R(H)

R

Br

R-MgX

ether

Nu

KOH, heat

H C

O O

R-X

H

N2H4

C

OH O

R(H) R

R C C

Na

C

N

NH2OH R(H)

R

C

R(H)

C

H3PO4

C OH

H

O C

heat

R

O H C

C

C

H

NaOH or

R

KOH, 5° C

C

C

R C

OH

O

C

C

C

R

R

C

R(H)

HOCH2CH2OH

O

cat. H+, "-H2O"

R

O

CH3MgBr

C

or CH3Li

R(H)

O C

H2O

R(H)

OH R

C

R(H) CH3

O

RCO3H

C

C

R-X

CN or

R-CN or R-N3

N3

Br

Br2

C

Fe

C

KMnO4

CH3OH

R-X EWG

C

H2O

heat

C OH

HO

R-OCH3 (+ HX)

EWG C

C

H2O H2SO4

C

C OH

H

H

HBr C

C

C

peroxides

C

Br

O H3C

C

CH3CH2CH2Cl

O Cl

AlCl3 CH3

AlCl3 C Br C

C

Br2

C Br

C

C

H2 Pt or Pd etc.

C

C

H

H...