Final Review Orgo 2 - Lecture notes 1-10 PDF

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Every flash card definition needed in ONE FULL YEAR of organic chem with Dr. Rizzo...

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FINAL REVIEW

1. Hydration of aldehydes and ketones (mechanism in acid/base, stability, and reactivity) 2. Acid and base catalyzed cyanohydrin formation (mechanism) 3. Hemiacetal, acetal, and cyclic acetal formation (mechanism and utility) 4. Hydrolysis of acetals 5. Imine and enamine formation (mechanism) 6. Wittig reaction and planning alkene synthesis via retrosynthetic analysis 7. Bayer-Villiger reaction (no mechanism) 8. Oxidation of aldehydes and ketones (all reaction conditions – no mechanisms) 9. Moffatt, Gatterman Koch, Hoesch, and Reimer-Tiemann reactions (no mechanisms) 10. Pinacol/pinacolone rearrangement (mechanism) 11. Clemmensen and Wolff-Kishner reductions (all reaction conditions – no mechanisms) 12. Enolate anion formation (base-catalyzed racemization of ketone where the chiral site is alpha to the carbonyl carbon) 13. Alkaloids and free base 14. Comparing basicity of amine compounds (mechanism and theory) 15. Extraction of amines from an organic layer 16. Phase Transfer Catalyst 17. Gabriel Synthesis and Haloform reaction (reaction conditions – no mechanisms) 18. Clarke-Eshweiller, Hofmann Degradation, and Cope elimination (reaction conditions – no mechanisms)

19. Protecting an amine to perform electrophilic aromatic substitution reactions 20. Diazotization of primary amines 21. Nitrosation of secondary amines 22. Diazonium ions (formation and utility) 23. Review ALL spectroscopy power point slides 24. Do ALL assigned homework problems 25. Use actual compounds (not R groups) when going through the list above. For example with the topic “hydration of aldehydes” use a compound like benzaldhyde. Show the mechanism. That way you can practice SPECTROSCOPY of the STARTING MATERIAL(S) and the PRODUCT(S) 26. Extra credit (MOTW and special topics in text) 27. Chair, Newman, Fischer projections 28. R/S notation 29. Stability of carbocation, carbonanion, carbon radical 30. Hybridization 31. MO theory and diagram of simple diatoms 32. Acid/base theory 33. Markovinikov and Zaitsev rules 34. SN1, SN2, E1, E2 reactions and mechanisms 35. Electrophilic aromatic substitution reactions 36. Alkane, Alkene, Alkyne reactions...