Title | Formula sheet and tables |
---|---|
Author | Logan Morris |
Course | Principles of Thermodynamics |
Institution | Texas A&M University |
Pages | 101 |
File Size | 5.8 MB |
File Type | |
Total Downloads | 30 |
Total Views | 136 |
Formula sheet with necessary equations along with all necessary tables....
Conversion Factors Mass and Density
Pressure
1 1 1 1 1 1
1 Pa
kg g/cm3 g/cm3 lb lb/ft3 lb/ft3
5 5 5 5 5 5
2.2046 lb 103 kg/m3 62.428 lb/ft3 0.4536 kg 0.016018 g/cm3 16.018 kg/m3
Length 1 1 1 1
cm m in. ft
5 5 5 5
0.3937 in. 3.2808 ft 2.54 cm 0.3048 m
Velocity 1 km/h 5 0.62137 mile/h 1 mile/h 5 1.6093 km/h
cm3 m3 L L in.3 ft3 gal gal
5 5 5 5 5 5 5 5
0.061024 in.3 35.315 ft3 1023 m3 0.0353 ft3 16.387 cm3 0.028317 m3 0.13368 ft3 3.7854 3 1023 m3
Force 1 1 1 1
N N lbf lbf
5 5 5 5
bar atm lbf/in.2 lbf/in.2 atm
1 N/m2 1.4504 3 1024 lbf/in.2 105 N/m2 1.01325 bar 6894.8 Pa 144 lbf/ft2 14.696 lbf/in.2
Energy and Specific Energy 1 1 1 1 1 1 1 1 1
J kJ kJ kJ/kg ft ? lbf Btu Btu Btu/lb kcal
5 1 N ? m 5 0.73756 ft ? lbf 5 737.56 ft ? lbf 5 0.9478 Btu 5 0.42992 Btu/lb 5 1.35582 J 5 778.17 ft ? lbf 5 1.0551 kJ 5 2.326 kJ/kg 5 4.1868 kJ
Energy Transfer Rate
Volume 1 1 1 1 1 1 1 1
1 1 1 1 1
5 5 5 5 5 5 5
1 kg ? m/s2 0.22481 lbf 32.174 lb ? ft/s2 4.4482 N
1W 1 kW 1 Btu/h 1 hp 1 hp 1 hp
5 5 5 5 5 5
1 J/s 5 3.413 Btu/h 1.341 hp 0.293 W 2545 Btu/h 550 ft ? lbf/s 0.7457 kW
Specific Heat 1 kJ/kg ? K 1 kcal/kg ? K 1 Btu/h ? 8R
5 0.238846 Btu/lb ? 8R 5 1 Btu/lb ? 8R 5 4.1868 kJ/kg ? K
Others 1 ton of refrigeration 5 200 Btu/min 5 211 kJ/min 1 volt 5 1 watt per ampere
Constants Universal Gas Constant
Standard Atmospheric Pressure
8.314 kJ/kmol ? K R 5 • 1545 ft ? lbf /lbmol ? 8R 1.986 Btu /lbmol ? 8R
1.01325 bar 1 atm 5 • 14.696 lbf/in.2 760 mm Hg 5 29.92 in. Hg
Standard Acceleration of Gravity
Temperature Relations
g5 e
9.80665 m /s 32.174 ft/s2
2
T18R2 5 1.8 T1K 2 T18C2 5 T1K2 2 273.15 T18F2 5 T18R2 2 459.67
MEEN315-700 SUMMER 2020
Page 1 of 4
YOU MAY REMOVE FORMULA SHEETS FROM THE EXAM. First Law of Thermodynamics
E = Q − W
(energy balance for closed system)
dE =Q dt
(energy rate balance for closed system)
dE cv = Qcv dt
cv
i
i
i +
i +
i
V2 + 2
−
i
e
e
e+
V2 + 2
e
(energy rate balance for control
volume)
0 = Qcv
cv
i
V2 + 2
i
− e
e
e+
V2 + 2
(energy rate balance for control volume at steady
e
state)
0 = Qcv
cv
1 −
2) +
(V1 2 −V2 2 ) + g ( z1 − z2 ) 2
(1-inlet, 1-exit control volume at
steady state)
Second Law of Thermodynamics 2 Q S 2 − S1 = + 1 T b
(closed system entropy balance)
Qj dS = + dt j Tj
(closed system entropy rate balance)
Qj dScv = + mi dt j Tj i 0= j
Qj Tj
i
−
+ mi i − i
e e
+ cv
(control volume entropy rate balance)
e
e e
+ cv
(control volume entropy rate balance at steady state)
e
Conservation of Mass
dmcv = mi − dt i e
e
m
i
i
=
e e
(Steady State)
MEEN315-700 SUMMER 2020
Page 2 of 4
Properties
E = KE + PE + U =
1 mV 2 + mgz + mu 2
h = u + pv
Thermodynamic Cylce
= =
Wcycle Qin
=
Wcycle
=
(Power cycle)
Qin
Qout Q = out Wcycle Wcycle
Qin Q = in Wcycle Wcycle
(Refrigeration cycle)
(Heat pump cycle)
Quality Equation
x=
mvapor
=
mliquid + mvapor
m vapor m
v = (1− x )vf + xvg = vf + x (vg − vf )
u =(1 − x) u f + xug = u f + x( u g − u f )
h = (1 − x )h f + xhg = h f + x (hg − h f )
s = (1 − x) sf + xsg = sf + x( sg − s f )
Isentropic Efficiencies
t =
Wt (Wt
actual s
(Turbine)
p =
ideal
Flow Relationships
m=
AV v
Boundary Work
W=
V2
V1
p dV
W = p(V2 − V1)
(Constant Pressure)
(Wp Wp
s
ideal actual
(Pump or compressor)
MEEN315-700 SUMMER 2020
W=
p2V2 − p1V1 1− n
Page 3 of 4
(Polytropic Process, pVn = constant)
V W = pV ln 2 V 1
(Polytropic Process, n=1)
Ideal Gas Relationships
pv = RT
pV = nRT
pV = mRT
𝑐𝑝 (𝑇) = 𝑐𝑣 (𝑇) + 𝑅
𝑘=
𝑐𝑝 (𝑇)
𝑐𝑝 (𝑇) =
𝑐𝑣 (𝑇)
𝑘𝑅 𝑘−1
c v (T ) =
du dT
u = cv T (at constant cv)
c p (T ) =
dh dT
h = cp T (at constant cp) T2
s (T2 ,v 2 ) − s (T1 ,v1 ) = c v (T ) T1
Z=
pv RT
pR =
p pc
T2
dT v + R ln 2 T v1
s (T2 , p 2 ) − s (T1 , p1 ) = s o (T2 ) − s o (T1 ) − R ln
TR =
T Tc
𝑅
𝑐𝑣 (𝑇) = 𝑘−1
s (T2 , p 2 ) − s (T1 , p1 ) = c p (T ) T1
p2 p1
v'R =
v RTc / p c
Ideal Gas Isentropic Relationships
p2 pr 2 = p1 pr 1 T2 v1 = T1 v2
v 2 v r2 = v1 vr 1 k−1
T2 p2 = T1 p1
(k −1)/k
Solid / Liquid Relationships
h = u = cT Tds Relations
T s = c ln 2 T1
p2 v1 = p1 v2
k
dT p − R ln 2 T p1
MEEN315-700 SUMMER 2020
Tds = du + pdv
Page 4 of 4
Tds = dh − vdp
Rankine Cycle
𝜂=
𝑊 𝑛𝑒𝑡 𝑄𝑖𝑛 𝑊𝑝/𝑚 /𝑚
Back work ratio (bwr) = 𝑊𝑡
Otto Cycle
𝜂=
𝑊𝑛𝑒𝑡 𝑄𝑖𝑛
𝜂 = 1−
1
(cold air-standard basis) r = compression ratio,
𝑟 𝑘−1
𝑛𝑒𝑡 𝑤𝑜𝑟𝑘 𝑓𝑜𝑟 𝑜𝑛𝑒 𝑐𝑦𝑐𝑙𝑒
Mean effective pressure (mep) = 𝑑𝑖𝑠𝑝𝑙𝑎𝑐𝑒𝑚𝑒𝑛𝑡 𝑣𝑜𝑙𝑢𝑚𝑒
Diesel Cycle
𝜂=
𝑊𝑛𝑒𝑡 𝑄𝑖𝑛
1
𝜂 = 1 − 𝑟 𝑘−1 [
ratio Mean effective pressure (mep) =
𝑟𝑐𝑘 −1
𝑘(𝑟𝑐 −1)
]
(cold air-standard basis) r = compression ratio, rc=cut off
𝑛𝑒𝑡 𝑤𝑜𝑟𝑘 𝑓𝑜𝑟 𝑜𝑛𝑒 𝑐𝑦𝑐𝑙𝑒 𝑑𝑖𝑠𝑝𝑙𝑎𝑐𝑒𝑚𝑒𝑛𝑡 𝑣𝑜𝑙𝑢𝑚𝑒
Index to Tables in SI Units Table A-1 Table A-2 Table A-3 Table A-4 Table A-5 Table A-6 Table A-7 Table A-8 Table A-9 Table A-10 Table A-11 Table A-12 Table A-13 Table A-14 Table A-15 Table A-16 Table A-17 Table A-18 Table A-19 Table A-20 Table A-21 Table A-22 Table A-23 Table A-24 Table A-25 Table A-26 Table A-27
Atomic or Molecular Weights and Critical Properties of Selected Elements and Compounds 890 Properties of Saturated Water (Liquid–Vapor): Temperature Table 891 Properties of Saturated Water (Liquid–Vapor): Pressure Table 893 Properties of Superheated Water Vapor 895 Properties of Compressed Liquid Water 899 Properties of Saturated Water (Solid–Vapor): Temperature Table 900 Properties of Saturated Refrigerant 22 (Liquid–Vapor): Temperature Table 901 Properties of Saturated Refrigerant 22 (Liquid–Vapor): Pressure Table 902 Properties of Superheated Refrigerant 22 Vapor 903 Properties of Saturated Refrigerant 134a (Liquid–Vapor): Temperature Table 907 Properties of Saturated Refrigerant 134a (Liquid–Vapor): Pressure Table 908 Properties of Superheated Refrigerant 134a Vapor 909 Properties of Saturated Ammonia (Liquid–Vapor): Temperature Table 912 Properties of Saturated Ammonia (Liquid–Vapor): Pressure Table 913 Properties of Superheated Ammonia Vapor 914 Properties of Saturated Propane (Liquid–Vapor): Temperature Table 918 Properties of Saturated Propane (Liquid–Vapor): Pressure Table 919 Properties of Superheated Propane Vapor 920 Properties of Selected Solids and Liquids: cp, r, and k. 924 Ideal Gas Specific Heats of Some Common Gases 925 Variation of cp with Temperature for Selected Ideal Gases 926 Ideal Gas Properties of Air 927 Ideal Gas Properties of Selected Gases 929 Constants for the van der Waals, Redlich–Kwong, and Benedict–Webb–Rubin Equations of State 933 Thermochemical Properties of Selected Substances at 298 K and 1 atm 934 Standard Molar Chemical Exergy, ech (kJ/kmol), of Selected Substances at 298 K and p0 935 Logarithms to the Base 10 of the Equilibrium Constant K 936
889
890
Tables in SI Units
Table A-1
TABLE A-1
Atomic or Molecular Weights and Critical Properties of Selected Elements and Compounds p c vc RTc
Substance
Chemical Formula
Acetylene Air (equivalent) Ammonia
C2H2 — NH3
26.04 28.97 17.03
309 133 406
62.8 37.7 112.8
0.274 0.284 0.242
Argon Benzene Butane
Ar C6H6 C4H10
39.94 78.11 58.12
151 563 425
48.6 49.3 38.0
0.290 0.274 0.274
Carbon Carbon dioxide Carbon monoxide
C CO2 CO
12.01 44.01 28.01
— 304 133
— 73.9 35.0
— 0.276 0.294
Copper Ethane Ethanol
Cu C2H6 C2H5OH
63.54 30.07 46.07
— 305 516
— 48.8 63.8
— 0.285 0.249
Ethylene Helium Hydrogen
C2H4 He H2
28.05 4.003 2.016
283 5.2 33.2
51.2 2.3 13.0
0.270 0.300 0.304
Methane Methanol Nitrogen
CH4 CH3OH N2
16.04 32.04 28.01
191 513 126
46.4 79.5 33.9
0.290 0.220 0.291
Octane Oxygen Propane
C8H18 O2 C3H8
114.22 32.00 44.09
569 154 370
24.9 50.5 42.7
0.258 0.290 0.276
Propylene Refrigerant 12 Refrigerant 22
C3H6 CCl 2F2 CHClF2
42.08 120.92 86.48
365 385 369
46.2 41.2 49.8
0.276 0.278 0.267
Refrigerant 134a Sulfur dioxide Water
CF3CH2F SO2 H2O
102.03 64.06 18.02
374 431 647.3
40.7 78.7 220.9
0.260 0.268 0.233
M (kg/kmol)
Tc (K)
pc (bar)
Zc 5
Sources: Adapted from International Critical Tables and L. C. Nelson and E. F. Obert, Generalized Compressibility Charts, Chem. Eng., 61: 203 (1954).
891
Tables in SI Units TABLE A-2
Properties of Saturated Water (Liquid–Vapor): Temperature Table Specific Volume m3/kg
Internal Energy kJ/kg
Temp. 8C
Press. bar
Sat. Liquid vf 3 10 3
Sat. Vapor vg
Sat. Liquid uf
Sat. Vapor ug
.01 4 5 6 8
0.00611 0.00813 0.00872 0.00935 0.01072
1.0002 1.0001 1.0001 1.0001 1.0002
206.136 157.232 147.120 137.734 120.917
0.00 16.77 20.97 25.19 33.59
2375.3 2380.9 2382.3 2383.6 2386.4
10 11 12 13 14
0.01228 0.01312 0.01402 0.01497 0.01598
1.0004 1.0004 1.0005 1.0007 1.0008
106.379 99.857 93.784 88.124 82.848
42.00 46.20 50.41 54.60 58.79
15 16 17 18 19
0.01705 0.01818 0.01938 0.02064 0.02198
1.0009 1.0011 1.0012 1.0014 1.0016
77.926 73.333 69.044 65.038 61.293
20 21 22 23 24
0.02339 0.02487 0.02645 0.02810 0.02985
1.0018 1.0020 1.0022 1.0024 1.0027
25 26 27 28 29
0.03169 0.03363 0.03567 0.03782 0.04008
30 31 32 33 34 35 36 38 40 45
Enthalpy kJ/kg Sat. Liquid hf
Entropy kJ/kg ? K
Evap. h fg
Sat. Vapor hg
Sat. Liquid sf
Sat. Vapor sg
0.01 16.78 20.98 25.20 33.60
2501.3 2491.9 2489.6 2487.2 2482.5
2501.4 2508.7 2510.6 2512.4 2516.1
0.0000 0.0610 0.0761 0.0912 0.1212
9.1562 9.0514 9.0257 9.0003 8.9501
.01 4 5 6 8
2389.2 2390.5 2391.9 2393.3 2394.7
42.01 46.20 50.41 54.60 58.80
2477.7 2475.4 2473.0 2470.7 2468.3
2519.8 2521.6 2523.4 2525.3 2527.1
0.1510 0.1658 0.1806 0.1953 0.2099
8.9008 8.8765 8.8524 8.8285 8.8048
10 11 12 13 14
62.99 67.18 71.38 75.57 79.76
2396.1 2397.4 2398.8 2400.2 2401.6
62.99 67.19 71.38 75.58 79.77
2465.9 2463.6 2461.2 2458.8 2456.5
2528.9 2530.8 2532.6 2534.4 2536.2
0.2245 0.2390 0.2535 0.2679 0.2823
8.7814 8.7582 8.7351 8.7123 8.6897
15 16 17 18 19
57.791 54.514 51.447 48.574 45.883
83.95 88.14 92.32 96.51 100.70
2402.9 2404.3 2405.7 2407.0 2408.4
83.96 88.14 92.33 96.52 100.70
2454.1 2451.8 2449.4 2447.0 2444.7
2538.1 2539.9 2541.7 2543.5 2545.4
0.2966 0.3109 0.3251 0.3393 0.3534
8.6672 8.6450 8.6229 8.6011 8.5794
20 21 22 23 24
1.0029 1.0032 1.0035 1.0037 1.0040
43.360 40.994 38.774 36.690 34.733
104.88 109.06 113.25 117.42 121.60
2409.8 2411.1 2412.5 2413.9 2415.2
104.89 109.07 113.25 117.43 121.61
2442.3 2439.9 2437.6 2435.2 2432.8
2547.2 2549.0 2550.8 2552.6 2554.5
0.3674 0.3814 0.3954 0.4093 0.4231
8.5580 8.5367 8.5156 8.4946 8.4739
25 26 27 28 29
0.04246 0.04496 0.04759 0.05034 0.05324
1.0043 1.0046 1.0050 1.0053 1.0056
32.894 31.165 29.540 28.011 26.571
125.78 129.96 134.14 138.32 142.50
2416.6 2418.0 2419.3 2420.7 2422.0
125.79 129.97 134.15 138.33 142.50
2430.5 2428.1 2425.7 2423.4 2421.0
2556.3 2558.1 2559.9 2561.7 2563.5
0.4369 0.4507 0.4644 0.4781 0.4917
8.4533 8.4329 8.4127 8.3927 8.3728
30 31 32 33 34
0.05628 0.05947 0.06632 0.07384 0.09593
1.0060 1.0063 1.0071 1.0078 1.0099
25.216 23.940 21.602 19.523 15.258
146.67 150.85 159.20 167.56 188.44
2423.4 2424.7 2427.4 2430.1 2436.8
146.68 150.86 159.21 167.57 188.45
2418.6 2416.2 2411.5 2406.7 2394.8
2565.3 2567.1 2570.7 2574.3 2583.2
0.5053 0.5188 0.5458 0.5725 0.6387
8.3531 8.3336 8.2950 8.2570 8.1648
35 36 38 40 45
Temp. 8C
H2O
ersions: Pressure Conv a MP 0.1 = r 1 ba 2 = 10 kPa
892
Tables in SI Units
TABLE A-2
(Continued )
H2O
Specific Volume m3 /kg Temp. 8C
Press. bar
Sat. Liquid 3 vf 3 10
50 55 60 65 70
.1235 .1576 .1994 .2503 .3119
75 80 85 90 95
.3858 .4739 .5783 .7014 .8455
Internal Energy kJ/kg
Sat. Vapor vg
Sat. Liquid uf
Sat. Vapor ug
1.0121 1.0146 1.0172 1.0199 1.0228
12.032 9.568 7.671 6.197 5.042
209.32 230.21 251.11 272.02 292.95
2443.5 2450.1 2456.6 2463.1 2469.6
1.0259 1.0291 1.0325 1.0360 1.0397
4.131 3.407 2.828 2.361 1.982
313.90 334.86 355.84 376.85 397.88
Enthalpy kJ/kg Sat. Liquid hf
Entropy kJ/kg ? K
Evap. hfg
Sat. Vapor hg
Sat. Liquid sf
Sat. Vapor sg
209.33 230.23 251.13 272.06 292.98
2382.7 2370.7 2358.5 2346.2 2333.8
2592.1 2600.9 2609.6 2618.3 2626.8
.7038 .7679 .8312 .8935 .9549
8.0763 7.9913 7.9096 7.8310 7.7553
50 55 60 65 70
2475.9 2482.2 2488.4 2494.5 2500.6
313.93 334.91 355.90 376.92 397.96
2321.4 2308.8 2296.0 2283.2 2270.2
2635.3 2643.7 2651.9 2660.1 2668.1
1.0155 1.0753 1.1343 1.1925 1.2500
7.6824 7.6122 7.5445 7.4791 7.4159
75 80 85 90 95
Temp. 8C
100 110 120 130 140
1.014 1.433 1.985 2.701 3.613
1.0435 1.0516 1.0603 1.0697 1.0797
1.673 1.210 0.8919 0.6685 0.5089
418.94 461.14 503.50 546.02 588.74
2506.5 2518.1 2529.3 2539.9 2550.0
419.04 461.30 503.71 546.31 589.13
2257.0 2230.2 2202.6 2174.2 2144.7
2676.1 2691.5 2706.3 2720.5 2733.9
1.3069 1.4185 1.5276 1.6344 1.7391
7.3549 7.2387 7.1296 7.0269 6.9299
100 110 120 130 140
150 160 170 180 190
4.758 6.178 7.917 10.02 12.54
1.0905 1.1020 1.1143 1.1274 1.1414
0.3928 0.3071 0.2428 0.1941 0.1565
631.68 674.86 718.33 762.09 806.19
2559.5 2568.4 2576.5 2583.7 2590.0
632.20 675.55 719.21 763.22 807.62
2114.3 2082.6 2049.5 2015.0 1978.8
2746.5 2758.1 2768.7 2778.2 2786.4
1.8418 1.9427 2.0419 2.1396 2.2359
6.8379 6.7502 6.6663 6.5857 6.5079
150 160 170 180 190
200 210 220 230 240
15.54 19.06 23.18 27.95 33.44
1.1565 1.1726 1.1900 1.2088 1.2291
0.1274 0.1044 0.08619 0.07158 0.05976
850.65 895.53 940.87 986.74 1033.2
2595.3 2599.5 2602.4 2603.9 2604.0
852.45 897.76 943.62 990.12 1037.3
1940.7 1900.7 1858.5 1813.8 1766.5
2793.2 2798.5 2802.1 2804.0 2803.8
2.3309 2.4248 2.5178 2.6099 2.7015
6.4323 6.3585 6.2861 6.2146 6.1437
200 210 220 230 240
250 260 270 280 290
39.73 46.88 54.99 64.12 74.36
1.2512 1.2755 1.3023 1.3321 1.3656
0.05013 0.04221 0.03564 0.03017 0.02557
1080.4 1128.4 1177.4 1227.5 1278.9
2602.4 2599.0 2593.7 2586.1 2576.0
1085.4 1134.4 1184.5 1236.0 1289.1
1716.2 1662.5 1605.2 1543.6 1477.1
2801.5 2796.6 2789.7 2779.6 2766.2
2.7927 2.8838 2.9751 3.0668 3.1594
6.0730 6.0019 5.9301 5.8571 5.7821
250 260 270 280 290
85.81 112.7 145.9 186.5 220.9
1.4036 1.4988 1.6379 1.8925 3.155
0.02167 0.01549 0.01080 0.006945 0.003155
1332.0 1444.6 1570.3 1725.2 2029.6
2563.0 2525.5 2464.6 2351.5 2029.6
1344.0 1461.5 1594.2 1760.5 2099.3
1404.9 1238.6 1027.9 720.5 0
2749.0 2700.1 2622.0 2481.0 2099.3