Chem 121 - Chapter 13 practice test with answers PDF

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Ch 13 Practice MC Problems 1. Which of the following statements is incorrect? A) Ionic bonding results from the transfer of electrons from one atom to another. B) Dipole moments result from the unequal distribution of electrons in a molecule. C) The electrons in a polar bond are found nearer to the more electronegative element. D) A molecule with very polar bonds can be nonpolar. E) Linear molecules cannot have a net dipole moment.

2.

Which of the following shows these molecules in order from most polar to least polar? A) CH4 > CF2Cl2 > CF2H2 > CCl4 > CCl2H2 B) CH4 > CF2H2 > CF2Cl2 > CCl4 > CCl2H2 C) CF2Cl2 > CF 2H2 > CCl2H2 > CH4 = CCl4 D) CF2H2 > CCl2H2 > CF2Cl2 > CH4 = CCl4 E) CF2Cl2 > CF2H2 > CCl4 > CCl2H2 > CH4

3.

Which of the following is polar? A) SiF4 B) XeF2 C) BCl3 D) NBr3 E) SBr6

4.

Which statement is correct? A) H2O is linear. B) The molecule ClO2 cannot be accurately described by a Lewis structure consistent with the octet rule. C) The diatomic molecule Cl2 is an example of a polar molecule. D) The bonds in LiF have a more covalent character than those in F 2. E) none of these

Use the following to answer question 5: Consider the following molecules. I. BF3 II. CHBr 3 (C is the central atom.) III. Br2 IV. XeCl2 V. CO VI. SF4 Select the molecule(s) that fit the given statement.

5. These molecules have a zero net dipole moment. A) III, V B) I, III, IV C) III, IV, V D) I, III, IV, VI E) none of them

6.

Select the best Lewis structure for acetone, CH3COCH3. H

H H

A) H

C

C O C H

H H

O

H H

C

C

C H

H H

B)

H

C)

H C C O H C H H H H

D)

H H C C O C H H H H H H

H C C C O H H

E)

7.

The Lewis structure for H3BO3 is A) H O B O H

O H B)

H

O

B

O

H

O

H

O H C)

H

O

B O H

D) H O

B

O

H

O

H

O H E)

H

O

B O H

8.

Which of the following is not a valid structure for N3–?

N

N

N

-

A)

N

N

N

N

N

N

N

N

N

-

B)

-

C)

D) E)

All are valid.

Use the following to answer question 9: Draw the Lewis structures of the molecules below, and use them to answer the following questions. I. BH3 II. NO2 III. SF6 IV. O3 V. PCl5 9.

Which of these molecules show resonance? A) I, II B) II, IV C) II, V D) III, IV E) III, V

10.

Which of the following has an incomplete octet in its Lewis structure? A) SO2 B) ICl C) SF2 D) F2 E) NO

11.

The molecule XCl5– has a square pyramidal shape. Which of the following atoms could be X? A) O B) P C) Xe D) S E) At least two of these atoms could be X.

12.

The Cl–Kr–Cl bond angle in KrCl4 is closest to A) 90°. B) 109°. C) 120°. D) 150°. E) 360°

13.

Of the following, which molecule has the largest bond angle? A) SO3 B) SF2 C) HCN D) H2S E) PF 3

14.

Select the correct molecular structure for SF4. A) linear B) bent C) pyramidal D) tetrahedral E) none of these

15.

Select the correct molecular structure for I3–. A) linear B) bent C) pyramidal D) tetrahedral E) none of these E) none of these

16.

How many of the following molecules and ions are linear? NCl3 NH4+ SCNCO2 NO2A) B) C) D) E)

0 1 2 3 4

17.

What type of structure does the XeOF 2 molecule have? A) pyramidal B) tetrahedral C) T-shaped D) trigonal planar E) octahedral

18.

Which ion is planar? A) PF 4+ B) CO32– C) SO32– D) ClO4– E) SCl5-

19.

Select the correct molecular structure for PO33–. A) pyramidal B) tetrahedral C) square planar D) octahedral E) none of these

Answers: 1. E 11. D

2. D 12. A

3. D 13. C

4. B 14. E

5. B 15. A

6. B 16. C

7. D 17. C

8. A 18. B

9. B 19. A

10. E...