Title | Lab 0 |
---|---|
Course | General Chemistry Laboratory |
Institution | Hunter College CUNY |
Pages | 3 |
File Size | 120.7 KB |
File Type | |
Total Downloads | 54 |
Total Views | 171 |
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Lab 0 Melting point Boiling Density Atomic (K) point (K) (g/mL) Element Number F 9 53 85 0.001553 Cl 17 172 239 0.002898 Br 35 266 332 3.1028 I 53 387 457 4.933
Radius (Å) 60 100 117 136
Ionization Energy (IE), (eV) 1681 1251 1140 1008
Electronegativity (EN) 4 3.2 3 2.7
Electron Affinity ((EA)kJ/mol) 328 kJ/mol 349 kJ/mol 324.6 kJ/mol 295.2 kJ/mol
Li Na K Rb Cs
3 11 19 37 55
454 371 337 312 302
1615 1156 1032 961 944
0.534 0.97 0.89 1.53 1.873
130 160 200 215 238
520 496 419 403 376
1 0.9 0.8 0.8 0.8
59.6 kJ/mol 52.8 kJ/mol 48.4 kJ/mol 46.9 kJ/mol 45.5 kJ/mol
Li Be B C N O F Ne
3 4 5 6 7 8 9 10
454 1560 2348
1615 2744 4273
0.534 1.85 2.34
63 54 53 24
77 90 85 27
0.001145 0.001308 0.001553 0.000825
130 99 84 75 71 64 60 62
520 900 801 1086 1402 1314 1681 2081
1 1.6 2 2.6 3 3.4 4
59.6 kJ/mol 0 kJ/mol 26.7 kJ/mol 153.9 kJ/mol 7 kJ/mol 141 kJ/mol 328 kJ/mol
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33
337 1115 1814 1941 2183 2180 1519 1811 1768 1728 1358 693 303 1211 1090
1032 1757 3109 3560 3680 2944 2334 3134 3200 3186 2835 1180 2477 3106
0.89 1.54 2.99 4.506 6 7.15 7.3 7.87 8.86 8.9 8.96 7.134 5.91 5.323 5.75
200 174 159 148 144 130 129 124 118 117 122 120 123 120 120
419 590 633 659 651 653 717 762 760 737 745 906 579 762 944
0.8 1 1.4 1.5 1.6 1.7 1.6 1.8 1.9 1.9 1.9 1.7 1.8 2 2.2
48.4 kJ/mol 2.37 kJ/mol 18.1 kJ/mol 7.6 kJ/mol 50.6 kJ/mol 64.3 kJ/mol 0 kJ/mol 15.7 kJ/mol 63.7 kJ/mol 112 kJ/mol 118.4 kJ/mol 0 kJ/mol 28.9 kJ/mol 119 kJ/mol 78 kJ/mol
34 35 36
494 266 116
958 332 120
4.809 3.102 0.0034
118 117 116
941 1140
2.6 195 kJ/mol 3 324.6 kJ/mol 0 kJ/mol
2.) Radius vs. Atomic Number PERIOD 4 ELEMENTS
Radius (Å)
Se Br Kr
200
200 190 180 170 160 150 140 130 120 110 100 18
174 159
148 144
130
124 129
20
22
24
120
118 117
123
122 26
28
120
30
118 117 116 120
32
34
36
38
Atomic Number
2.) As the atomic number of the elements in period 4 increase, the atomic radius decreases. The reasoning for this is as the numbr of protons increases, the nuclear charge attracts the electrons more strongly. This pulls the electrons closer to the nucleus resulting in a smaller radius.
6.) Melting points/Boiling points of Alkali metals vs. Atomic number 1800 1600
1615
1400
1156
1200
1032
1000
961
944
312
302
800 600
454
371
400
337
200 0 0
5
10
15
20
25
30
35
40
45
50
55
60
Atomic Number Melting point (K) Boiling point (K)
Linear (Melting point (K)) Exponential (Boiling point (K))
6.) As the atomic number increases, both the melting and boiling points decrease. When alkali metals are melted, the metallic bond is weakened enough for the atoms to move more freely
and is broken completely when the boiling point is reached. The boiling point is much higher than the melting point because a higher amount of energy is required to break the chemical bonds.
9.) Density vs. Boiling Point of Halogens 500
457
450
Boiling point (K)
400
332
350 300
239
250 200 150
85
100
50 0 0
0.5
1
1.5
2
2.5
3
3.5
4
4.5
5
Density (g/mL)
9.) The boiling point of halogens increases as the density of the element increases. Although density increases as atomic number increases, the density has no clear trend. However, as you go down the group, the boiling point increases due to the increasing strength of Van der Waals forces.
10.) Electronegativity vs. Atomic Number Period 2 Elements 4.5
4
Electronegativity (EN)
4
3.4
3.5
3 2.6
3 2.5
2 1.6
2 1.5
1
1 0.5 0 2
0 3
4
5
6
7
8
9
10
11
Atomic Number
10.) As you go down Period 2, the electronegativity increases. As the atomic number increases and the radius decreases, there is more attraction of the nucleus towards electron cloud. The effective nuclear charge increases. There is a drop at Neon because it is a noble gas, and it has no electronegativity because it has a full octet and does not need to pull electrons....