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PROJECT 1 1. SYNTHESIS OF H3BCO a. Hyperconjugation is the process of stabilizing interaction that is from the interaction of the electrons in a σ-bond that is next to an empty or partially filled p-orbital or a π-orbital. This increases stability of the system. Negative hyperconjugation is the process of stabilizing interaction that is from a filled p-orbital or π-orbital to stabilize the molecule, increasing electron density of the σ-bond. b. The paper that identified the synthesis of H3BCO was Carbonyl Compounds of Boron and Their Isomers by Anne Skancke,and Joel F. Liebman. In this article it discusses that it is likely because of the low activation barriers may be cause for its instability rather than its thermodynamics of H3BCO c. The calculated bond length of BC in H3BCO is 1.55Á and the strength of the bond is 25 kcal/ mol. This was discussed in an article titled Carbonyl Compounds of Boron and Their Isomers by Anne Skancke,and Joel F. Liebman. 2. ACTIVATION a. A catalyst is a substance that increases the rate of reaction by decreasing the activation energy, but is not consumed by the reaction. b. Ammonia Is difficult to activate by transition metals because ammonia creates Warner complexes, and these require a lot of activation energy. .E–H Bond Activation of Ammonia and Water by a Geometrically Constrained Phosphorus(III) Compound Dr.  Thomas P. Robinson Daniel  M. DeRosa   Prof.  Dr. Simon Aldridge Prof.   Dr. Jose M. Goicoechea c. The T-shaped system facilitates the oxidative addition of ammonia, primary amines and alcohols. The phosphorus is t-shaped because of bonding geometry. The phosphorus is connected to 3 other atoms and lone pairs. The lone pair has more repulsive than an atom would and causes the bond angles to be less that 109.5 degrees d. P-Stereogenic and Non-P-Stereogenic Ir–MaxPHOX in the Asymmetric Hydrogenation of N- Aryl Imines. Isolation and X-ray Analysis of Imine

Iridacycles by Ernest Salomó Pep Rojo , Pol Hernández-Lladó, Antoni Riera, and Xavier Verdaguer.

3. Questions a. The Department of Chemistry at the University of Calgary: 50+ years of discovery Canadian  Journal of Chemistry (2016), 94, (4), vii-x. Publisher: (Canadian Science Publishing, ) CODEN:CJCHAG ISSN:0008-4042. b. Oxidative Addition Reactions of Organoplatinum(II) Complexes with Nitrogen-Donor Ligands Louis  M. Rendina and Richard  J. Puddephatt c. The synthesis and structure of a paramagnetic Lewis base adduct of antimony pentachloride,trans-[MnII(CNSbCl5)(CO)2{P(OEt)3}(dppm)] [SbCl6] Journal  of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1999), (18), 3191-3195. Publisher: (Royal Society of Chemistry, ) CODEN:JCDTBI ISSN:0300-9246. References 1. Leo J. Malone, R. W. Parry. The Preparation and Properties of the Boranocarbonates,Vol. 6, No. 4, April 1967 Skancke A.,Liebman F. J.,Carbonyl Compounds of Boron and Their Isomers., J. Phys. Chem. 1994, 98,13215-13220 2. Robinson P. T.. De  Rosa M.D., Aldridge S., Goicoechea M.E–H Bond Activation of Ammonia and Water by a Geometrically Constrained Phosphorus(III) Compound., Angewandte Chemie International EditionVolume  54, Issue 46 3. D. Bellamy,N.   C. Brown, N.  G. Connelly,A.   G. Orpen .,the  synthesis and structure of a paramagnetic Lewis base adduct of antimony pentachloride, trans-[MnII(CNSbCl5)(CO)2{P(OEt)3}(dppm)][SbCl6].,Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1999), (18), 3191-3195.

4. Cramb D, Armstrong   D., Krueger  P. , Baumgartner T, Thurbide  K. , Causton  A.,Sutherland   T., The Department of Chemistry at the University of Calgary: 50+ years of discovery 5. Louis M. Rendina and Richard  J. Puddephatt., Oxidative Addition Reactions of Organoplatinum(II) Complexes with Nitrogen-Donor Ligands.,Organometallics 1985, 4, 7, 1221-1223 (Article) 6. Salomó E., Rojo P. , Hernández-Lladó P. , Riera A., and Verdaguer X.,  P-Stereogenic and Non-P-Stereogenic Ir–MaxPHOX in the Asymmetric Hydrogenation of N - Aryl Imines. Isolation and X-ray Analysis of Imine Iridacycles.,J. Org. Chem.  2018, 83, 8, 4618–4627...